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It will show a list of files in your cache which you can double click to open, even while offline.
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To get to the cached Office files, open the Office Upload Center and select All Cached Files from the drop-down list next to the Refresh button. It will only cache the files that you opened with an Office application (such as Word, Excel, or PowerPoint). In Office RT, the Office Document Cache is not proactive in downloading your Office files from a OneDrive or a SharePoint site. The offline portion as mentioned above will not work for Office RT, but there is a workaround. Note: Clearing the Office Document Cache by clicking Delete cached files or enabling Delete files from the Office Document cache when they are closed will delete the document content from the cache, but a listing of files that have been opened is kept in the cache and stored on your computer. Files older than the maximum number of days will be removed from the cache only when there are no changes pending upload. You can set the maximum number of days to keep files in the Office Document cache by adjusting the Days to keep files in the Office Document Cache as necessary. You can manage the Microsoft Office Upload Center notification icon by disabling notifications and turning off the display of the icon. You can manage the Office Document Cache settings by customizing the settings in the Microsoft Office Upload Center. The Office Document Cache is used by the Microsoft Office Upload Center to give you a way to see the state of files you're uploading to a server-keeping track of how uploads are progressing and whether any files need your attention.
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